The kinetics of methane steam reforming over a ni o catalyst. This name is commonly retained even when other feedstocks e. Steam methane reforming is the most widely used process for the generation of hydrogen. Abstract methane steam reforming experiments were carried out at atmospheric pressure for temperatures between 873 and 1073 k and by varying the partial pressure of methane and steam to achieve s. Optimal design and decision for combined steam reforming. In smr, methane reacts with steam under 325 bar pressure 1 bar 14. Co are also active for the methane steam reforming 25. Kinetics study and modelling of steam methane reforming process over a nioal 2o 3 catalyst in an adiabatic packed bed reactor s. Steam reforming is endothermicthat is, heat must be supplied to the process for the reaction to proceed. Advanced steadystate modelling and optimisation of natural gas reforming reactors.
These onsite units provide a compact, efficient, and flexible alternative to other hydrogen supply schemes. Methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. On the catalytic aspects of steammethane reforming a. Pdf on the modeling of steam methane reforming researchgate. Onsite hydrogen generation by steam methane reforming what its like to be a hydrogen molecule duration.
Steam reforming of natural gas the most economical and highly preferable process with the resources of eritrea is steam reforming of natural gas. Autothermal reforming of natural gas to synthesis gas. Hydrogen production by steam reforming chemical engineering. The methane conversion to synthesis gas mixture of co and h 2 can be realized by different processes like the methane steam reforming msr with h 2 o 1234, dry methane reforming with.
C2pt catalyst process technology by gerard b hawkins managing director 2. Life cycle assessment of hydrogen production via natural gas. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. Due to its maturity, high efficiency, and relatively low cost, steam reforming is considered a viable option for supporting a future hydrogen economy.
The design of the steam reforming process is in part dictated by these constraints. In order to obtain acceptable reaction rates a catalyst is required to accelerate the process. The effects of reaction parameters, including reaction temperature and space velocity, on hydrogen production via steam reforming of methane srm were investigated using lab and benchscale. The methane steam reforming was studied by 26 in a fixed bed tubular quartz micro reactor with cobalt catalyst. The catalyst showed stability and activity at a feed molar ratio sc21, wf 0.
This is largely due to its cost effectivness in obtaining a high level of purity in its produced hydrogen. Steam reforming of methane in a synthesis gas from biomass gasification h hiblot, i zieglerdevin, r fournet, pierrealexandre glaude to cite this version. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. Presentation about steam reforming modeling and simulatino. Pdf steam methane reforming is an endothermic reaction which is considered as one of the main processes in hydrogen and syngas. Preliminary equipment design for onboard hydrogen production. Steam reforming of methane in a synthesis gas from biomass. A considerable effort has been put into investigations of the kinetics of methane steam reforming. International journal of hydrogen energy, elsevier.
Mechanistic investigation of methane steam reforming over ce. Catalytic steam reforming an overview sciencedirect topics. Lca is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes. The steam methane reforming process can be broken down into five distinct steps. Methane steam reforming reaction behaviour in a packed bed. Kinetics, catalysis and mechanism of methane steam reforming. Hydrogen production via steam reforming with co2 capture. The most studied technology for hydrogen production from fossil fuels is steammethane reforming smr, in which methane reacts with steam to produce a. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. Globally, it was shown that the catalyst 10% nickel content has an important effect on the catalytic performances of solids i. Methane steam reforming reaction behaviour in a packed. For decades, downfired steam methane reformer furnaces have utilized flue gas tunnels coffins along the radiant section floor to collect and improve flue gas flow uniformity.
The next subsection describes the specific technical issues associated with the high pressure atr approach especially when combined with carbon dioxide recirculation. Steam reforming of methane in a synthesis gas from biomass gasification. The equilibrium composition out of the steam reformer is shown in fig. The second is the steam methane reformer, which converts feedstock and steam to syngas mainly hydrogen and carbon monoxide at high temperature and moderate pressure. The experimental study has been done in a plug flow reactor under a near atmospheric pressure 1. Mechanistic considerations for methane steam reforming msr were derived onthebasisoflangmuirhinshelwood. Hydroprime plants offer many advantages over traditional supply modes such as electrolytic plants, conventional steam methane plants and truckdelivered bulk hydrogen.
On the catalytic aspects of steammethane reforming a literature. Advanced modelling and optimisation of natural gas reforming. Hydrogen production steam methane reforming smr pdf, hydrogen fact sheet, archived from the original pdf on 4 february 2006. A life cycle assessment lca of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases, as well as other major environmental consequences.
Steam reforming or steam methane reforming is a method for producing syngas hydrogen and. H hiblot, i zieglerdevin, r fournet, pierrealexandre glaude. Methane steam reforming on supported nickel, effect of. Steam methane reforming smr for biogas the process of smr can also be utilized for the production of hydrogen from biogas. Models for the steam reforming process and the combined process were developed and extended mitigation cost was suggested to evaluate co2 reduction of the overall process. Actually, a small amount of steam is introduced into the process, but this reaction is a bigger endothermic reaction than the catalytic steam reforming reaction. Steam reforming free download as powerpoint presentation. Meanwhile, the steam methane reformer refers only to the fired chemical reactor in which reaction takes place. Steam methane reforming smr is a chemical process used in the gas manufacturing industry to produce hydrogen on a large scale. Research directions hydrogen production technologies are in various stages of development. In steammethane reforming, methane reacts with steam under 325 bar pressure 1 bar 14. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h.
The first units commissioned in the 1930s were run on light hydrocarbon feedstock at atmospheric pressure l, it took until 1962 for a 15atm steam reformer to come onstream in the united kingdom using liquid hydrocarbon feedstock 24. The effects of reaction parameters, including reaction temperature and space velocity, on hydrogen production via steam reforming of methane srm were investigated using lab. Linde is a leading supplier of steam reformer plants with more than 200 constructed units producing capacities of synthesis gas from 300 to over 200,000 nm. The steam reforming plant consists of four basic sections bressan et al. Both alternatives have been widely studied due to the use of mature techniques, i. Steam methane reforming, or smr, processes feedstocks, ranging from natural gas to light naphtha, mixed with steam to produce a hydrogen rich syngas effluent, with a typical h 2 co ratio of 3. The main purpose of this technology is hydrogen production. It is reversible and strongly endothermic, and according to the principle of le chatelier it must be carried out at high. The desulfurized hydrocarbon feed is mixed with superheated process steam in accordance with the steamcarbon relationship necessary for the reforming process.
Nibased catalysts for low temperature methane steam reforming. Life cycle assessment of hydrogen production via natural. Steam reforming of methane and other hydrocarbons has been an extremely important process for the production of synthesis gas 46. Redefining steam methane reformer performance in hydrogen. Scribd is the worlds largest social reading and publishing site. Some technologies, such as steam methane reforming, are already commercial and can be used in the near term. Steam methane reforming is the most common and economical way to make hydrogen. Mahmud school of chemical and process engineering, the university of leeds, ls2 9jt, uk. An investigation of hydrogen generation via steam reforming of. Pdf benchscale steam reforming of methane for hydrogen. The hydrogen produced contains less than 10 ppmv of carbon oxides, but can achieve only a hydrogen concentration between 92 and 97 vol% depending on the severity of the reforming reaction. Nial2o4 in the reduced and unreduced state as well as nial4o7 in the reduced state are active and stable for methane dry reforming due to the presence of 4fold coordinated oxidized nickel.
Kinetics study and modelling of steam methane reforming. Methane steam reforming an overview sciencedirect topics. Comparison of catalyst geometries for methane steam reforming. The methane conversion to synthesis gas mixture of co and h 2 can be realized by different processes like the methane steam reforming msr with h 2. Mechanistic investigation of methane steam reforming over. Despite the fact that hydrogen can be produced in numerous ways, the most interesting but also promising part is the production of hydrogen through electrolysis of water. May 19, 2011 onsite hydrogen generation by steam methane reforming what its like to be a hydrogen molecule duration.
The simulation and optimal design of the commercial process requires information on the intrinsic kinetics. Jul 28, 20 steam reforming the basics of reforming 1. An experimental and modelling study of the pyrolysis and of the steam reforming of methane in mixtures representative of a gas produced from biomass gasification has been performed. Advanced modelling and optimisation of natural gas. For more than 40 years the catalyzed hydroearbonsteam reforming reaction has been of commercial value. Comparison of catalyst geometries for methane steam. Natural gas reforming, steam methane reforming, autothermal reforming, gproms, modelling, optimisation. Steam reforming before development of psa with a polybed psa system, the co 2 removal system and methanator become redundant. Fbcr was used for detailed modelling of the catalyst beds considering rigorous intraparticle mass and heat transport.
Thus we concentrated more on design of a complete process plant for hydrogen production from steam reforming of natural gas. Pdf an industrial steam methane reformer optimization using. Because the dry methane reforming process could generate synthesis gas from carbon dioxide, it could decrease the co2 emissions from the existing steam reforming process. Methane steam reforming on solid catalysts is the wellestablished commercial process for the production of hydrogen and synthesis gas. Pdf modeling and simulations of steam methane reforming smr process to produce hydrogen and or syngas are presented in this article. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. Keywords nickel catalysts, zno, methane steam reforming, hydrogen 1. Catalytic reforming of methane in the presence of co2. Under these conditions, the catalyst presents the average h2co.
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